1D Polymeric Iodoantimonates(III) with 1-Methylpyridinium and 3-Bromo-1-methylpyridinium Cations: Structures and Properties

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Дәйексөз келтіру

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Аннотация

The reactions of SbI3 with iodides of cations of the pyridinium family in a mixture of acetonitrile and acetone afford two polymeric iodoantimonate complexes: (1-MePy)[SbI4] (I) and (3-Br-1-MePy)[SbI4] (II). Specific features of the crystal structures are determined by X-ray diffraction (XRD). The thermal stability of compounds I and II is evaluated by thermogravimetry. The optical forbidden bandgaps are estimated from the diffuse reflectance spectra.

Авторлар туралы

I. Shentseva

Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences

Novosibirsk, Russia

A. Usol’tsev

Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences

Novosibirsk, Russia

N. Korobeinikov

Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences; Novosibirsk State University

Email: korobeynikov@niic.nsc.ru
Novosibirsk, Russia; Novosibirsk, Russia

S. Adonin

Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences; Favorskii Institute of Chemistry, Siberian Branch, Russian Academy of Sciences

Novosibirsk, Russia; Irkutsk, Russia

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