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详细

In this work, a new approach to the synthesis of iron pentacarbonyl Fe(CO)₅ is studied, offering a more stable and less energy-intensive alternative to traditional methods for obtaining metal carbonyls—the inductive flow levitation (IFL). The IFL technology allows the process to be conducted at relatively low pressure (~5 bar). To optimize the synthesis of metal carbonyls, the reaction setup was modernized using a cryotrapping system, which consists of a quartz ampoule immersed in a Dewar vessel, maintained at a temperature of -40°C using a thermostat. During experiments, the composition of the resulting gas mixture was analyzed using gas chromatography and mass spectrometry methods, enabling high-precision identification and monitoring of the synthesized product directly during the reaction process.

作者简介

A. Vorotyntsev

Nizhny Novgorod State University named after N.I. Lobachevsky

Email: an.vorotyntsev@gmail.com
Gagarin Ave., 23, Building 2, Nizhny Novgorod, 603950 Russia

A. Markov

Nizhny Novgorod State University named after N.I. Lobachevsky

Gagarin Ave., 23, Building 2, Nizhny Novgorod, 603950 Russia

E. Dokin

Nizhny Novgorod State University named after N.I. Lobachevsky

Gagarin Ave., 23, Building 2, Nizhny Novgorod, 603950 Russia

A. Kapinos

Nizhny Novgorod State University named after N.I. Lobachevsky

Gagarin Ave., 23, Building 2, Nizhny Novgorod, 603950 Russia

A. Emelyanov

Nizhny Novgorod State University named after N.I. Lobachevsky

Gagarin Ave., 23, Building 2, Nizhny Novgorod, 603950 Russia

P. Grachev

Nizhny Novgorod State University named after N.I. Lobachevsky

Gagarin Ave., 23, Building 2, Nizhny Novgorod, 603950 Russia

V. Medov

Nizhny Novgorod State University named after N.I. Lobachevsky

Gagarin Ave., 23, Building 2, Nizhny Novgorod, 603950 Russia

A. Petukhov

Nizhny Novgorod State University named after N.I. Lobachevsky

Gagarin Ave., 23, Building 2, Nizhny Novgorod, 603950 Russia

参考

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