Using Immobilized Hybrid Composites Based on Mixed Polyoxometalates As Catalysts for the Oxidation of Heteroatomic Compounds

V. M. Zelikman; Зеликман В. М.; K. I. Maslakov; Маслаков К. И.; I. A. Ivanin; Иванин И. А.; I. G. Tarkhanova; Тарханова И. Г.

doi:10.31857/S0044453723090273

Using Immobilized Hybrid Composites Based on Mixed Polyoxometalates As Catalysts for the Oxidation of Heteroatomic Compounds

Authors: Zelikman V.M.¹, Maslakov K.I.¹, Ivanin I.A.¹, Tarkhanova I.G.¹
Affiliations:
1. Faculty of Chemistry, Moscow State University
Issue: Vol 97, No 9 (2023)
Pages: 1239-1247
Section: CHEMICAL KINETICS AND CATALYSIS
Submitted: 26.02.2025
Published: 01.09.2023
URL: https://rjdentistry.com/0044-4537/article/view/668656
DOI: https://doi.org/10.31857/S0044453723090273
EDN: https://elibrary.ru/XQBDHD
ID: 668656

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Abstract
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Abstract

A set of silica gel-immobilized compounds is synthesized that consists of ethylimidazole cations and anions of phosphotungstic acid (lacunar (PW11) or mixed (PW11M), where M = Zn, Ni, Cu, Co, Mn). The composition and textural characteristics of the compounds are determined by physicochemical means (IR spectroscopy, XPS, SEM/EDX, adsorption). The synthesized heterogeneous composites are active in the oxidation of sulfur- and nitrogen-containing components of petroleum feedstocks with hydrogen peroxide. A comparative analysis is performed of the samples’ catalytic properties in the oxidation of both individual substrates (thiophene, dibenzothiophene, methyl phenyl sulfide, pyridine) and their mixtures.

Keywords

oxidative desulfurization, oxidative denitrogenation, polyoxometalates, immobilized catalysts

References

Tanimu A., Alhooshani K. // Energy Fuels. 2019. V. 33. № 4. P. 2810.
Shafi R., Hutchings G.J. // Catal. Today. 2000. V. 59. P. 423.
Houda S., Lancelot C., Blanchard P. et al. // Catalysts. 2018. V. 8. № 9. P. 344.
Shafiq I., Shafique S., Akhter P. et al. // J. Clean. Prod. 2021. V. 294. P. 2.
Есева Е.А., Акопян А.В., Анисимов А.В. и др. // Нефтехимия. 2020. Т. 60. № 5. С. 586.
Rajendran A., Cui T., Fan H. et al. // J. Mater. Chem. A. 2020. V. 8. № 5. P. 2246.
Liu F., Yu J., Qazi A.B. et al. // Environ. Sci. Technol. 2021. V. 55. № 3. P. 1419.
Ионные жидкости: теория и практика (Проблемы химии растворов). Отв. ред. А.Ю. Цивадзе. Иваново: Ивановский издательский дом, 2019. С. 672.
Yang L., Franco V., Mock P. et al. // Environ. Sci. Technol. 2015. 49. P. 14409.
Aghbolagh Z.S., Khorrami M.R.K., Rahmatyan M.S. // J. Iran Chem. Soc. 2022. V. 19. P. 219.
Mello P. de A., Nunes M.A.G., Bizzi C.A. et al. Evaluation of Ultrasound Systems for Sulphur and Nitrogen Removal form Diesel Fuels by Oxidative Treatment, in: 13th Meet. Eur. Soc. Sonochemistry. 2012. P. 148.
Ali-Zade A.G., Buryak A.K., Zelikman V.M. et al. // New J. Chem. 2020. V. 4. P. 6402.
Bryzhin A.A., Gantman M.G., Buryak A.K. et al. // Appl. Catal. B: Environ. 2019. T. 257. P. 117938.
Тарханова И.Г., Вержичинская С.В., Буряк А.К. и др. // Кинетика и катализ. 2017. Т. 58. № 4. С. 384.
Choi J.H., Kim J.K., Park D.R., Kang T.H. // J. Mol. Catal. A: Chem. 2013. V. 371. P. 111.
Nogueira L.S., Ribeiro S., Granadeiro C.M. et al. // Dalton Trans. 2014. V. 43. P. 9518.
Patel A., Narkhede N., Singh S. et al. // Catal. Rev. Sci. Eng. 2016. V. 58 (3). P. 337.
Li J., Yang Zh., Li S. et al. // J. Ind. Eng. Chem. 2020. V. 82. P. 1.
Xu Y., Ma W.-W., Dolo A. et al. // RSC Adv. 2016. V. 6. P. 66841.
Ismagilov Z., Yashnik S., Kerzhentsev M. et al. // Catal. Rev. Sci. Eng. 2011. V. 53. № 3. P. 199.
Tarkhanova I.G., Zelikman V.M., Gantman M.G. //Appl. Catal. A. 2014. V. 470. P. 81.
Jonnevijlle F., Tourné C.M., Tourné G.F. // Inorg. Chem. 1982. V. 21. P. 2742.
Jalil P.A., Faiz M., Tabet N. et al. // J. Catal. 2003. V. 217. № 2. P. 292.
Li J., Luo L., Tan W. et al. // Environ. Sci. Pollut. Res. 2019. V. 26. № 33. P. 34248.
Imran M., Zhou X., Ullah N. et al. // Chemistry Select. 2017. V. 2. № 27. P. 8625.
Fiorio J.L., Braga A.H., Guedes C.L.B. et al. // ACS Sustain. Chem. Eng. 2019. V. 7. № 19. P. 15874.
García-López E.I., Marcì G., Krivtsov I. et al. // J. Phys. Chem. C. 2019. V. 123. № 32. P. 19513.
Hernández-Cortez J.G., Manríquez M., Lartundo-Rojas L. et al. // Catal. Today. 2014. V. 220–222. P. 32.
Molina J., Fernández J., del Río A.I. et al. // Appl. Surf. Sci. 2011. V. 257. № 23. P. 10056.
Zatsepin D.A., Mack P., Wright A.E. et al. // Phys. Status Solidi A. 2011. V. 208. № 7. P. 1658.
Alam A.U., Howlader M.M.R., Deen M.J. // ECS J. Solid State Sci. Technol. 2013. V. 2. № 12. P. 515.
Konga L., Lia G., Wang X. // Catal. Lett. 2004. V. 92b. № 3. P. 163.
Максимов А.Л., Нехаев А.И. // Нефтехимия. 2020. Т. 60. № 2. С. 172.
Брыжин А.А., Руднев В.С., Лукиянчук И.В. и др. // Кинетика и катализ. 2020. Т. 61. № 2. С. 262.
Ростовщикова Т.Н., Локтева Е.С., Шилина М.И. и др. // Журн. физ. химии. 2021. Т. 95. № 3. С. 348.
Pyridine: A Useful Ligand in Transition Metal Complexes, Edited by P.P. Pandey, 2018. P. 84.