New Catalyst Systems for the Polymerization of Norbornene and Its Derivatives Based on Cationic Palladium Cyclopentadienyl Complexes

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The catalytic properties of systems based on [Pd(Cp)(L)n]m[BF₄]m (where Cp = η5-C5H5; n = 2, m = 1: L = tris(orthomethoxyphenyl)phosphine, triphenylphosphine, tris(2-furyl)phosphine (TFP), n = 1, m = 1: L = 1,1'-bis(diphenylphosphino)ferrocene, 1,3-bis(diphenylphosphino)propane, 1,4-bis(diphenylphosphino)butane, 1,5-bis(diphenylphosphino)pentane; n = 1, m = 2 or 3: L = 1,6-bis(diphenylphosphino)hexane) in the addition homoand copolymerization of norbornene (NB) and its derivatives have been studied. These complexes can be activated with the Lewis-acids (BF₃ ∙ OEt2 or AlCl3). The productivity of the [Pd(Cp)(PPh3)2][BF₄]/BF₃ ∙ OEt2 catalyst system in the polymerization of norbornene is up to 188800 molNB molPd⁻¹. The homopolymerization of 5-methoxycarbonylnorbornene and copolymerization of NB with 5-methoxycarbonylnorbornene or 5-phenylnorbornene were studied in the presence of BF₃ ∙ OEt2 and [Pd(Cp)(L)2][BF₄] (L = PPh3 or TFP). A hypothesis for the catalyst’s formation via the intramolecular rearrangement of the η5-Cp ligand into the η1-Cp form upon interaction with a Lewis acid is suggested. The structure of the [Pd(Cp)(TFP)2]BF₄ (I) was determined by X-ray diffraction. In the crystal structure of I, the palladium coordination sphere is characterized by a slight distortion of the square planar geometry of the central atom, and the cyclopentadiyl fragment is in an eclipsed conformation. Based on the XRD data, the steric hindrance of the TFP ligand was estimated (the cone angle is 149°).

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D. Suslov

Irkutsk State University, Department of Chemistry; Irkutsk State University, Research Institute of Oil and Coal Chemical Synthesis

编辑信件的主要联系方式.
Email: suslov@chem.isu.ru
俄罗斯联邦, K. Marksa st., 1, Irkutsk, 664003; Irkutsk, 664003

M. Pakhomova

Irkutsk State University, Department of Chemistry; Irkutsk State University, Research Institute of Oil and Coal Chemical Synthesis

Email: suslov@chem.isu.ru
俄罗斯联邦, K. Marksa st., 1, Irkutsk, 664003; Irkutsk, 664003

M. Bykov

Irkutsk State University, Department of Chemistry; Irkutsk State University, Research Institute of Oil and Coal Chemical Synthesis

Email: suslov@chem.isu.ru
俄罗斯联邦, K. Marksa st., 1, Irkutsk, 664003; Irkutsk, 664003

T. Orlov

Irkutsk State University, Research Institute of Oil and Coal Chemical Synthesis; National Research Irkutsk State Technical University, School of High Technologies

Email: suslov@chem.isu.ru
俄罗斯联邦, Lermontov St., 83, K. Marksa st., 1, Irkutsk, 664003; Irkutsk, 664074

Z. Abramov

Irkutsk State University, Department of Chemistry; Irkutsk State University, Research Institute of Oil and Coal Chemical Synthesis

Email: suslov@chem.isu.ru
俄罗斯联邦, K. Marksa st., 1, Irkutsk, 664003; Irkutsk, 664003

A. Suchkova

Irkutsk State University, Research Institute of Oil and Coal Chemical Synthesis

Email: suslov@chem.isu.ru
俄罗斯联邦, K. Marksa st., 1, Irkutsk, 664003

P. Abramov

Nikolaev Institute of Inorganic Chemistry SB RAS

Email: suslov@chem.isu.ru
俄罗斯联邦, Akad. Lavrentieva ave., 3, Novosibirsk, 630090

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