Microstructure and deformation behavior of novel metal–ceramic laminated composites Ta/Ti3Al(Si)C2–TiC

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New metal–ceramic laminated composites Ta/Ti3Al(Si)C2–TiC were obtained by spark plasma sintering. The samples were synthesized at a temperature of 1250°C and a pressure of 50 MPa for 5 min. For the formation of composites, preceramic paper with a powder filler based on the MAX phase Ti3Al(Si)C2, as well as and metal foils made of tantalum, were used. The phase composition, microstructure and elemental composition were analyzed by X-ray diffraction, scanning electron microscopy and energy dispersive X-ray spectroscopy, respectively. It was found that as a result of sintering, dense multilayer composites were formed, consisting of tantalum metal layers, ceramic layers containing Ti3Al(Si)C2, TiC and Al2O3 phases, as well as reaction layers ~13 μm thick at the metal–ceramic interface, enriched with Ta, Al and Si. Based on mechanical test data, the ultimate bending strength of the obtained composites was determined (σbs = ~430 MPa). Metal–ceramic laminated composites with a refractory tantalum layer were shown to exhibit a ductile fracture mechanism, accompanied by a more than fourfold increase in absolute deformation compared to a Ti3Al(Si)C2-based ceramic composite. This is achieved due to deflection, branching of cracks at the metal–ceramic interface and plastic deformation of tantalum layers.

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作者简介

A. Abdulmenova

National Research Tomsk Polytechnic University

编辑信件的主要联系方式.
Email: ava75@tpu.ru
俄罗斯联邦, Tomsk, 634050

E. Kashkarov

National Research Tomsk Polytechnic University

Email: egor_kashkarov@mail.ru
俄罗斯联邦, Tomsk, 634050

D. Krotkevich

National Research Tomsk Polytechnic University

Email: ava75@tpu.ru
俄罗斯联邦, Tomsk, 634050

N. Travitzky

Friedrich-Alexander-Universitat Erlangen–Nürnberg

Email: ava75@tpu.ru

Department of Materials Science, Glass and Ceramics

德国, Erlangen, 91054

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2. Fig. 1. Diffraction patterns of pre-ceramic paper (1) and the cross-section of the sintered laminated Ta/TAC–TiC composite (2).

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3. Fig. 2. SEM image of the cross-section of the laminated Ta/TAC–TiC composite. RS – reaction layer.

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4. Fig. 3. SEM image and corresponding distribution maps of reaction layer elements.

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5. Fig. 4. Stress-strain curves of a monolithic TAC sample (1) and a laminated Ta/TAC–TiC composite (2).

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6. Fig. 5. SEM images of the cross-section of the fracture surface (a) and the crack propagation region in the laminated Ta/TAC–TiC composite (b).

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